• Syllabus
• Full playlist of lectures on YouTube
DAY 1: Strong Inference + Main Group Organometallics
• Worksheet • Lecture Video • Handout
DAY 2: Organotransition Metal Complexes: History, Structure, and Bonding I
• Worksheet • Lecture Video • Handout
DAY 3: Organotransition Metal Complexes: History, Structure, and Bonding II
• Worksheet • Lecture Video • Handout 1 • Handout 2
DAY 4: Elementary Reactions I
• Worksheet • Lecture Video
DAY 5: Elementary Reactions II
• Worksheet • Lecture Video
DAY 6: Elementary Reactions III
• Worksheet • Lecture Video
DAY 7: Carbenes and Other M–C and M–X Multiple Bonds I
• Worksheet • Lecture Video
DAY 8: Carbenes and Other M–C and M–X Multiple Bonds II
• Worksheet • Lecture Video
DAY 9: GUEST – Coordination Chemistry of Isonitrile Complexes (J. Figueroa, UCSD)
DAY 10: Principles of Catalysis and Ancillary Ligand Design
• Worksheet • Lecture Video
DAY 11: Catalytic Hydrogenation
• Worksheet • Lecture Video
DAY 12: MIDTERM
DAY 13: Catalytic Carbonylation
• Worksheet • Lecture Video
DAY 14: Wacker- and Heck-Type Alkene Additions
• Worksheet • Lecture Video • Handout
DAY 15: Allylic Substitution Chemistry
• Worksheet • Lecture Video • Handout
DAY 16: Catalytic Cross-Coupling
• Worksheet • Lecture Video • Handout
DAY 17: GUEST –Advances in Site-Selective Cross-Coupling (S. Neufeldt, Montana State)
DAY 18: GUEST – Organometallic Fluorination Reactions (N. Ball, Pomona)
DAY 19: GUEST – Application, Mechanism, and Catalyst Activation in the Real World (E. Simmons & M. Joannou, Bristol Myers Squibb)
DAY 20: GUEST – Natural and Artificial Metalloenzymes (H. Renata, Rice)
• Lecture Video • Handout
DAY 21: Olefin Metathesis
• Worksheet • Lecture Video • Handout 1 • Handout 2
DAY 22: PROJECT – Wikipedia Project Presentations.
2023 Problem Sets, Midterm, and Final (Grading Keys Available Upon Request)
• Problem Set 1
• Problem Set 2
• Midterm
• Final
Wikipedia Project
Since 2017, the Scripps Organometallics class created >50 new Wikipedia pages on topics relevant to coordination chemistry, organometallics, and catalysis. Below are representative articles voted among the best by the class for each year:
2023
• Kharasch—Sosnovsky Reaction
• Metallophotoredox
• Oxidative Phenol Coupling
• Organogermanium Chemistry
• Texaphyrin
2021
• Concerted Metalation Deprotonation
• Crystal Sponge
• Conia-Ene Reaction
• Organotechnicium Compound
• Metal–Ligand Cooperativity
• Shuttle Catalysis
2019
• Artificial Metalloenzymes
• Cross Electrophile Coupling
• Philippe Barbier
• Metallo-Ene Reaction
• Beta-Carbon Elimination
2017
• Activation of Cyclopropanes by Transition Metals
• Mukaiyama Hydration
• Spin Forbidden Reactions
• Tsuji–Wilkinson Decarbonylation Reaction
• Ugi’s Amine
