Pd(COD)(DQ), the stable monometallic Pd(0) precatalyst developed by our group in collaboration with Bristol Myers Squibb has been commercialized by MilliporeSigma and can now be conveniently ordered on a variety of scales (#938718). Try Pd(COD)(DQ) in cross-couplings or other reactions where you would normally turn to Pd2(dba)3. Combine with a phosphine or NHC ligand of choice in situ, add reactants, and you’ll be off to the races.
For a link to the pre-print describing Pd(COD)(DQ), click here: https://chemrxiv.org/engage/chemrxiv/article-details/65e8f798e9ebbb4db918a09f
For a link to the ordering page on MilliporeSigma, click here: https://www.sigmaaldrich.com/US/en/product/aldrich/938718?srsltid=AfmBOooU1-xETxrRkgPu0QwZueJ4SDwMfSpFj_sH6KmVRm_GNa0n4F9F
Molecular Complexity through Catalysis 